CHEM 2319-2
Quiz #1 Answers
Dr. Bachrach
January 25, 2008

1) Draw the Lewis Dot Structure for the following molecule with molecular formula C5H6N+

 

2) Which atom or atoms carry positive charge in the above molecule?

Notice that all carbons are the same here – every carbon makes one single bond to a neighbor carbon, one double bond to the other neighbor carbon and a single bond to a hydrogen, and they have no unshared electrons. Therefore, they will all have the same formal charge. The same can be said for the nitrogen – it is bonding identically in the two resonance structures – the difference is which carbon it is double bonded to. So let’s calculate the formal charge for the H, C, and N atoms:

FC(X) = #valence e- on atom X - # bond to atom X - # unshared e-on atom X

FC(H) = 1 – 1 – 0 = 0

FC(C) = 4 – 4 – 0 = 0

FC(N) = 5 – 4 – 0 = +1, so nitrogen carries the positive charge in this molecule.